Facile Rearrangement of a Bis(N-heterocyclic carbene)borate Chelate Ligand and Access to [:GeX]+Complexes (X = H, Cl)
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چکیده
منابع مشابه
Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3.
N-heterocyclic olefins (NHOs), IPrCH2 (1) and SIPrCH2 (2) (IPrCH2 = {N(2,6-iPr2C6H3)CH}2CCH2 and SIPrCH2 = {N(2,6-iPr2C6H3)CH2}2CCH2), react with HSiCl3 and afford IPrCH(SiHCl2) (3) and SIPrCH(SiHCl2) (4), respectively. Compounds 3 and 4 have been isolated in almost quantitative yield. Interestingly, treatment of the silylene IPr·SiCl2 with 1 also affords 3, where silylene insertion into a C–H ...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2015
ISSN: 1434-1948
DOI: 10.1002/ejic.201500434